Label abbreviations descriptions

MALEIC ANHYDRIDE†

Chemical Identification
CAS # 108-31-6
Formula

C₄H₂O₃
Synonyms

cis-butenedioic anhydride; 2,5-furanedione; maleic acid anhydride; toxilic anhydride

Physical Properties
Physical description Colorless needles, white lumps, or pellets with an irritating, choking odor.
Boiling point 396°F Molecular weight 98.06
Freezing point/melting point 127°F Vapor pressure 0.2 mmHg
Flash point 218°F Vapor density
Specific gravity 1.43 at 59°F Ionization potential 9.90 eV
Lower explosive limit (LEL) 1.4% Upper explosive limit (UEL) 7.1%
NFPA health rating 3 NFPA fire rating 1
NFPA reactivity rating 1 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA
Analyte code (IMIS no.) 1618
Sampling group
Sampler/Sampling media GFFs coated with veratrylamine (3,4-dimethoxybenzylamine) and di-n-octyl phthalate [SLTC100]
Sampling time*
Sampling volume (TWA)*

60 L
Sampling flow rate (TWA)*

0.5 L/min
Sampling volume (STEL/Peak/C)*
 

 
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments HPLC
Method reference OSHA 86 (fully validated)
Notes
 

Store filters under refrigeration and use within 1 month. Small interfering peaks start appearing after that time.
Special requirements
 

These media are prepared by SLTC as needed and are not available for immediate shipment. Please allow time for SLTC to prepare these media prior to sampling.

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method
Wipe Sampler/Sampling media
 

 
Bulk Method
 

 

On-Site Screening Techniques
Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits
OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA
 

0.25 ppm (1 mg/m³)

 REL-TWA
 

0.25 ppm (1 mg/m³)

 TLV-TWA
 

0.01 mg/m³ (inhalable fraction and vapor) [2010]

 PEL-TWA
 

0.1 ppm (0.4 mg/m³)
PEL-STEL
 

 

 REL-STEL
 

 

 TLV-STEL
 

 

 PEL-STEL
 

 
PEL-C
 

 

 REL-C
 

 

 TLV-C
 

 

 PEL-C
 

 
Skin notation
 

N

 Skin notation
 

N

 Skin notation
 

N

 Skin notation
 

N
Notes:
 

See 29 CFR 1910.1000 Table Z-1.

 Notes:
 

 

 Notes:
 

dermal sensitization (DSEN), respiratory sensitization (RSEN)

 Notes:
 

 
Health factors:  See NIH-NLM PubChem. IDLH
 

10 mg/m³
Carcinogenic classifications: TLV-A4 Notes:
 

 
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
 

0.2 ppm/5 ppm/20 ppm

Additional Resources and Literature References

Last Updated Date : 01/04/2021